Oxide Nanostructures: Growth, Microstructures, and by Avanish Kumar Srivastava

By Avanish Kumar Srivastava

Nanomaterials, their synthesis, and estate stories were an obsession with glossy present physicists, chemist, and fabrics scientists for his or her titanic array of technological implications and the amazing method their houses are changed or better whilst the scale dimensions are lowered to the area of nanometers. even though nanomaterials, for many useful reasons were in life because the remotest prior of civilization, it's only within the previous few a long time that the sphere has been gaining the eye that it merits from the medical and commercial fraternity. loads of this has to do with the vast development we made in instruments to check and represent those materials.

Metal oxides were one of many good documented and most well-liked branches of nanomaterials revolution with oxides reminiscent of TiO2, ZnO, CuO, Fe3O4, Cr2O3, Co3O4, MnO2 and plenty of extra being an essential component to numerous technological developments and commercial functions. From eco-friendly energy matters like photovoltaic cells to rechargeable batteries, from drug supply brokers to antimicrobial and beauty items, from superconductor fabrics to semiconductors and insulators, steel oxides were omnipresent by way of either advertisement prerogatives and study highlights. This e-book is just committed in the direction of this particular portion of nanomaterials with an objective to partly entry the technology relating the oxides of metals.

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Extra info for Oxide Nanostructures: Growth, Microstructures, and Properties

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1. 1 Various synthesis methods employed for metal oxide nanomaterials. 29 30 Metal Oxide Nanomaterials The physical or aerosol methods of synthetic procedures include vapor deposition, spray pyrolysis and ϐlame deposition of metal organic precursors. Vapor deposition technique to produce metal oxide nanomaterials, starting from a supersaturated vapor of the metals is among the earliest methods to produce the metal oxide nanoparticles. They generally involve two steps: ϐirst, a metallic nanophase powder is condensed under inert convection gas after a supersaturated vapor of the metal is obtained inside a chamber.

Their availability in various shapes and sizes and applications in diversiϐied ϐields of industrial and technological necessities have channelized the metal oxide nanomaterials to be as much a hot ϐield of research today as carbon nanotubes (CNTs) and graphene. In fact, the surge in the interest level in metal oxides can be well documented by the following plot, which gives a relative idea about the number of papers published on two of the most important metal oxides (TiO2 and ZnO) during the last 15 years.

Hu et al. reported ultrahigh speciϐic capacitance of ca. 1300 F g–1 and excellent charge/discharge behavior at 1000 mV s–1 obtained from RuO2 · xH2O nanotubes [157]. Zang et al. prepared cone-shaped polypyrrole composite of RuO2 and its speciϐic capacitance was reported to be 302 G g–1 [158]. Nanocomposite of CNT and RuO2 nanoparticles (with a mass ratio of 7:6) was reported to show a speciϐic capacitance of 953 F g–1 [159]. However, it is not widely used yet due to the high processing cost, narrow operating voltage (~1 V) rarity of Ru and the toxic nature of RuO2, despite being the 17 18 Metal Oxide Nanomaterials best supercapacitor material in terms of high speciϐic capacitance (1580 F g–1) and reversibility [157].

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