Linear Triatomic Molecules - SCS, SCS+, SCS++, SeCSe, CCN, by G. Guelachvili, K. Narahari Rao (auth.), G. Guelachvili

By G. Guelachvili, K. Narahari Rao (auth.), G. Guelachvili (eds.)

The creation basically reviews molecular theories and equations, at the foundation of which lots of the evaluated information are tested. particular reviews relating to a few of the molecules thought of within the subvolumes II/20B1-4 are retained within the current creation because of their attainable normal applicability. more information of sensible curiosity (list of symbols with their definitions, devices, desk of conversion components, notations for the bands and effort degrees, desk of energy-related devices and chosen primary constants, etc.) can be given.
The tables are preceded by means of an extra index to aid the hunt for particular info. with a purpose to preserve their consistency and their optimal skill to breed info, molecular constants are said while attainable from an identical calculation of a given set of measurements. The subvolume ends with a reference section.

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The authors assumed Doppler profiles and as such made use of Eq. 15 K, c is sample concentration (isotopic abundance was used for the isotopic sample concentration), and l is the absorption path length in cm. 2 C2N CCN (CCN) ~ ~ A 2 ∆ (000) ← Χ 2 Π (000) vibronic transition Experimental studies (a) Kakimoto and Kasuya [82Kak] made use of cw dye laser excitation spectroscopic techniques to obtain experimental measurements of this vibronic transition observed between 21 205 - 21 335 cm–1. To take advantage of the precision achieved in their laboratory data, these authors employed the rotational term value expressions given in [75Bol] which are an extended version of the original work of Hougen [62Hou].

Let us denote the Hund’s case (a) basis functions by | J, W, MJ, S, S Ò, where J is the quantum number for the total angular momentum J = N + S, W and MJ are the components of J along the molecular z axis and space-fixed Z axis, respectively, and S and S represent the spin angular momentum and its component along the molecular z axis. Since the orbital angular momentum L is zero and S is unity, W (= S) is equal to 0, or ± 1. The energy values were calculated by direct diagonalization of the energy matrices constructed using the symmetry adapted linear combinations of Hund’s case (a) functions, | J, W, MJ , S, S, ± Ò = (1/2)1/2 (| J, W, MJ , S, S Ò ± | J, – W, MJ , S, – S Ò).

Introduction Vibrational level 0110 P 0000 S LIX Vibronic species Energy level designation [79Gau] [86Sea] k2Su– X˜ 2Pg (010) k2Su– G (010, 2Su–) E (2S –) 2 D3/2 u X˜ 2Pg (010) 2D3/2 u G (010, 2D3/2 u) E (2D3/2) 2 D5/2 u X˜ 2Pg (010) 2D5/2 u G (010, 2D5/2 u) E (2D5/2) m2Su+ X˜ 2Pg (010) m2Su+ G (010, 2Su+) E (2S + ) 2 P1/2 g X˜ 2Pg (000) 2P1/2g 2 P3/2 g X˜ 2Pg (000) 2P3/2 g 2r ASO (2D) ASO (2P) Fig. 1. Energy level diagram indicating the vibronic levels associated with the vibrational levels 0000 and 0110 in the ground electronic state X˜ 2Pg of CO2+.

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